1. Consider this reaction: Cl2 ---> 2CI . If AH° of this reaction is 245 kJ/mol, then what is the shortest wavelength that will initiate the reaction Atmospheric pressure 101325 Pascal (1.0 atm), R = 8.314 J molk', density of re 12 a ka (m3
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- Constants: • c = 2.9979 x 108 m/s • h = 6.626 x 10-34 J s per one photon • R = 8.314 J/(K mol) = 0.08206 Latm/(K mol) = 6.022 x 1023 particles/mol NA = RH = 1.097 x 107 m1 = 2.178 x 10-18 J . You conduct a Photoelectric Experiment and shine light with a wavelength of 5.34 x 10-7 meters onto a metal surface. Electrons are ejected with a Kinetic Energy of 79.0 kJ/mol. What is the Binding Energy (in kJ/mol) for the metal?7.) Why is the photodissociation of oxygen more important than the photoionization of oxygen at altitudes below about 90 km. A) because the pressure is higher B) because of the higher temperature C) because all of the lower energy photons required for photoionization have already been absorbed D) because all of the higher energy photons required for photoionization have already been absorbedReactions of the type OH + CF,Cl, –→HOF + CFCI2 are conceivable tropospheric sinks for CFCS. Can you deduce why they don't occur, given that C–F bonds are much stronger than 0–F bonds?
- The stratospheric ozone 1O32 layer helps to protect usfrom harmful ultraviolet radiation. It does so by absorbingultraviolet light and falling apart into an O2 molecule and anoxygen atom, a process known as photodissociation.O31g2¡O21g2 + O1g2Use the data in Appendix C to calculate the enthalpy changefor this reaction. What is the maximum wavelength a photoncan have if it is to possess sufficient energy to cause thisdissociation? In what portion of the spectrum does thiswavelength occur?(a) When chlorine atoms react with atmospheric ozone,what are the products of the reaction? (b) Based on averagebond enthalpies, would you expect a photon capable ofdissociating a C—Cl bond to have sufficient energy to dissociatea C—Br bond? (c) Would you expect the substanceCFBr3 to accelerate depletion of the ozone layer?At large interatomic separations, an alkali halide moleculeMX has a lower energy as two neutral atoms, M + X; atshort separations, the ionic form (M+)(X-) has a lowerenergy. At a certain distance, Rc, the energies of the twoforms become equal, and it is near this distance that theelectron will jump from the metal to the halogen atom during a collision. Because the forces between neutral atomsare weak at large distances, a reasonably good approximation can be made by ignoring any variation in potentialV(R) for the neutral atoms between Rc and R - `. For theions in this distance range, V(R) is dominated by theirCoulomb attraction.(a) Express Rc for the first ionization energy of the metalM and the electron affinity of the halogen X.(b) Calculate Rc for LiF, KBr, and NaCl using data fromAppendix F.
- Peroxyacyl nitrates contain two relatively weak bonds that can be broken by low-energy photons. The weakest is the N−O bond in the nitrate functional group of the molecule with a standard bond-dissociation energy of 201 kJ/mol. What is the longest wavelength of a photon, in nanometers, that has enough energy to cause the photodissociation of the weakest bond. Assume all energy of the photon is efficiently used for the photodissociation.14.6) The mean lifetime of an electronically excited molecules is 1.0 x 10^-8 s. If the emission of the radiation occurs at 610 nm, what are the uncertainties in frequency (Δν) and wavelength (Δλ)?10:37 EO O * E ll 48% Vol) LTE1 This document contains ink, shapes and images that a. III. The Pauli Exclusion Principle serves to identify each electron. Four numbers (n, I, m, and m.) are assigned to each guest in the hotel. The number n, is the principle quantum number which corresponds to the "floor" the electron is on. The letter 1 describes the room layout or the "floor area" in which the electron is staying (s = 0, p = 1, d= 2, f= 3, etc.). There is only one s type room on each floor; there are three p type rooms on each floor from the second up; there are five d type rooms on each floor starting with the third floor and going up; and there are seven f type rooms on each floor starting with the fourth floor and moving upwards. The letter m, describes the specific room (most analogous to a room number.) Figure 1 shows a diagram of the holel rooms available by floor. Figure 1: The Atomic Hotel by Floor d f 4 Floor n=1, 2, 3... -1 0 +1 -2 -1 0 +1 +2 -3 -2 -1 0 +1 +2 +3 Room type /…
- 08. HW Module 8 (due 10/17) * OWLV2 | Online teaching and lear X genow.com/ilrn/takeAssignment/takeCovalentActivity.do?locator=Dassignment-take Paused [References] TUTOR Photon Energy I Some chemical reactions, such as formation of ozone in Earth's stratosphere, can be initiated by light that has a wavelength less than some particular value. Calculate the longest wavelength (nm) that can provide an energy of at least 420 kJ/mol. Submit Show Approach Hide Tutor Steps TUTOR STEP What is the frequency of light, in hertz, that has the necessary energy? E = 6.98×10-19 J/photon ZH X Recheck Next (3 of 5) 21st attempt Incorrect Use Planck's equation, E= hv or v = to determine the frequency. h= 6.626 × 10-34 J s Previous Next Submit Answer Try Another Version 5 item attempts remainin Show Hint 7:00 PM 10/17/2021 ch +66 LEGO 6. H.Covalent bonds in a molecule absorb radiation in the IR re-gion and vibrate at characteristic frequencies.(a) The C—O bond absorbs radiation of wavelength 9.6 μm.What frequency (in s⁻¹) corresponds to that wavelength?(b) The H—Cl bond has a frequency of vibration of 8.652x10^13Hz. What wavelength (in μm) corresponds to that frequency?With all species in the gas phase, which one would require the highest energy? Al-> Al+ +e-, Si -> Si+ + e-, S -> S+... , Mg-> Mg+..., P->P+..